Champions League holders Barcelona will take on Arsenal in the Champions League round of 16, while Chelsea face Paris Saint-Germain.
Barca claimed European glory for a fifth time after beating Juventus 3-1 in June’s final, as Luis Enrique’s charges completed a memorable Treble.
Arsenal reached the knockout phase after claiming a 3-0 win at Olympiakos in the final group game to finish second, behind Bayern.
Rafa Benitez’s Real Madrid take on Serie A side Roma, while last season’s runners-up Juventus face Bundesliga giants Bayern Munich.
Gent, the first will Belgian side to reach the last 16 since Anderlecht in 2000-01, face German outfit Wolfsburg.
Ties to be played between Feb. 16, 17; 23, 24; and March 8, 9; 15, 16:
Dynamo Kyiv vs Manchester City
Benfica vs Zenit
PSV vs Atletico Madrid
Juventus vs Bayern Munich
Arsenal vs Barcelona
PSG vs Chelsea
Roma vs Real Madrid
Gent vs Wolfsburg